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AP Chemistry/Unit 4: Chemical Reactions
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Principles of Gravimetric Analysis

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Consider the following data from a gravimetric analysis experiment.

Description Mass (g)
Unknown Alkali Hydroxide Sample 4.33
Cu(OH)2Cu(OH)_2 precipitate 3.81

Reaction: Cu2++2 OH−→Cu(OH)2Cu^{2+}+2\,OH^-\rightarrow Cu(OH)_2

All of the following statements regarding the experiment are true EXCEPT:

A

The balanced reaction Cu2++2 OH−→Cu(OH)2Cu^{2+}+2\,OH^-\rightarrow Cu(OH)_2 is used to relate moles of hydroxide to precipitate formed.

B

Gravimetric analysis relies on the law of conservation of mass to correlate precipitate mass with the amount of the analyte.

C

Errors in weighing the precipitate can lead to incorrect determination of the unknown compound.

D

The mass of Cu(OH)2Cu(OH)_2 precipitate exceeding the original sample mass would violate conservation of mass.

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