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AP Chemistry/Unit 6: Thermodynamics
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Ionic Properties and Hydration Energy
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Experimental data indicate that smaller ions with higher charges have more negative hydration energies. Which of the following statements best explains this observation?

A

The hydration energy is determined solely by the size of the ion, with charge having no significant influence on the energy observed.

B

Higher charge density leads to stronger electrostatic attractions with water molecules, resulting in more negative hydration energies.

C

The experimental data are inconclusive, and no reliable relationship between ionic size, charge, and hydration energy can be established.

D

Ions with lower charges actually exhibit greater negative hydration energies due to reduced electrostatic repulsion in aqueous solutions.

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