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AP Chemistry/Unit 7: Equilibrium
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Extent of Reaction at Equilibrium

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For the reaction PCl5(g)⇌PCl3(g)+Cl2(g)\mathrm{PCl}_5(g) \rightleftharpoons \mathrm{PCl}_3(g) + \mathrm{Cl}_2(g), the equilibrium constant is K=0.0211K = 0.0211 at 500 K. If an initial 0.100 mol of PCl5(g)\mathrm{PCl}_5(g) is placed in a 2.00 L container and allowed to reach equilibrium, which statement is most accurate?

A

Approximately half of the PCl5 decomposes

B

More than 90% of the original PCl5 remains unreacted

C

PCl5 completely decomposes to PCl3 and Cl2

D

Equal amounts of PCl5, PCl3, and Cl2 are present

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