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AP Chemistry/Unit 7: Equilibrium
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Reaction Quotient and Equilibrium Shift

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Consider the equilibrium reaction 2NO2(g)N2O4(g)2*NO_2 (g) \rightleftharpoons N_2O_4 (g). If the initial concentrations are [NO₂] = 0.8 M and [N₂O₄] = 0.2 M, and the equilibrium constant is K = 0.5, calculate the reaction quotient Q=[N2O4][NO2]2Q = \frac{[N_2O_4]}{[NO_2]^2} and determine the net direction in which the reaction will shift.

A

The reaction shifts to the right because Q (≈ 0.3125) is less than K.

B

The reaction first shifts left then right due to kinetic factors.

C

No net shift occurs because Q equals K.

D

The reaction shifts to the left because Q is greater than K.

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