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AP Chemistry/Unit 9: Applications of Thermodynamics
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Electrolytic Cell Voltage Requirement
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For an electrolytic cell to operate, the applied voltage must have a magnitude greater than that of the standard cell potential. Which of the following statements best accounts for this requirement?

A

Since the cell reaction is non-spontaneous under standard conditions, the applied voltage must be greater than the standard cell potential to drive the reaction.

B

The required applied voltage can be lower than the standard cell potential because temperature variations compensate for the deficit.

C

The applied voltage is irrelevant to the operation of an electrolytic cell since the cell potential remains unchanged regardless of external input.

D

An electrolytic cell operates spontaneously, so the external voltage only needs to approximate the standard cell potential.

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