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AP Chemistry/Unit 9: Applications of Thermodynamics
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Galvanic Cell Potential and Concentration
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A galvanic cell is constructed using Ag⁺/Ag and Ni²⁺/Ni half-cells. Given the standard reduction potentials $$E^{0} ext{(Ag}^+/ ext{Ag)} = +0.80 ext{ V}$$ and $$E^{0} ext{(Ni}^{2+}/ ext{Ni)} = -0.25 ext{ V}$$, which of the following modifications would result in the largest increase in the cell potential?

A

Increasing [Ni²⁺] by a factor of 100

B

Increasing the surface area of the Ni electrode

C

Increasing [Ag⁺] by a factor of 100

D

Decreasing [Ag⁺] by a factor of 100

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