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AP Chemistry/Unit 9: Applications of Thermodynamics
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Le Châtelier's Principle and Electrochemical Cells
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A student attempts to apply Le Châtelier’s principle to predict the effect of increasing [Cu2+] in a Cu/Zn electrochemical cell. Why is this approach fundamentally flawed?

A

Le Châtelier’s principle only applies to gaseous reactions

B

Electrochemical cells operate under non-equilibrium conditions

C

The reaction is too fast for equilibrium principles to apply

D

Concentration changes don’t affect electrochemical systems

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