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AP Chemistry/Unit 9: Applications of Thermodynamics
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Nernst Equation and Le Châtelier's Principle
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A student observes that adding more Zn2+ to a Zn/Cu cell decreases the cell potential. The student concludes this follows Le Châtelier’s principle. What is wrong with this conclusion?

A

Adding Zn2+ should increase the cell potential

B

The potential change is from the Nernst equation, not equilibrium shifts

C

The reaction is irreversible so no principles apply

D

Le Châtelier’s principle only applies to temperature changes

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