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AP Chemistry/Unit 9: Applications of Thermodynamics
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Standard Potential of a Reversed Half-Reaction

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Which of the following statements best explains why reversing a half-reaction changes the sign of its standard potential?

A

The sign of the electrode potential remains unchanged when the half-reaction is reversed because the energy change is intrinsic.

B

Reversing the half-reaction has no effect on the cell potential since standard potentials are invariant with respect to reaction direction.

C

When reversed, the half-reaction’s potential is doubled, as both directions contribute additively to the overall potential.

D

Reversing the half-reaction flips the sign of the electrode potential, since the reduction potential becomes the oxidation potential.

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