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AP Chemistry/Unit 9: Applications of Thermodynamics
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Voltaic Cell Voltage and Equilibrium
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In a voltaic cell experiment, a student observes a decrease in voltage over time and concludes that the reaction quotient (Q) is approaching the equilibrium constant (K), leading to zero voltage. What is the mistake in this conclusion?

A

An increase in Q always increases the cell voltage, regardless of K.

B

Decreasing voltage indicates the cell is moving away from equilibrium.

C

Voltage decreases as Q approaches K, but it does not drop to zero until Q equals K.

D

Voltage is independent of the reaction quotient in voltaic cells.

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